Lithium–sulfur batteries are a promising energy-storage technology due to their relatively low cost and high theoretical energy density. However, one of their major technical problems is the shuttling of soluble polysulfides between electrodes, resulting in rapid capacity fading. Here, we present a metal–organic framework (MOF)-based battery separator to mitigate the shuttling problem. We show that the MOF-based separator acts as an ionic sieve in lithium–sulfur batteries, which selectively sieves Li+ ions while e ciently suppressing undesired polysulfides migrating to the anode side. When a sulfur-containing mesoporous carbon material (approximately 70 wt% sulfur content) is used as a cathode composite without elaborate synthesis or surface modification, a lithium–sulfur battery with a MOF-based separator exhibits a low capacity decay rate (0.019% per cycle over 1,500 cycles). Moreover, there is almost no capacity fading after the initial 100 cycles. Our approach demonstrates the potential for MOF-based materials as separators for energy-storage applications.
上传时间: 2017-11-23
上传用户:653357637
书名:bessel functions and their applications 作者:B. G. Korenev
上传时间: 2019-12-30
上传用户:944905540
Abstract—In the future communication applications, users may obtain their messages that have different importance levels distributively from several available sources, such as distributed storage or even devices belonging to other users. This scenario is the best modeled by the multilevel diversity coding systems (MDCS). To achieve perfect (information-theoretic) secrecy against wiretap channels, this paper investigates the fundamental limits on the secure rate region of the asymmetric MDCS (AMDCS), which include the symmetric case as a special case. Threshold perfect secrecy is added to the AMDCS model. The eavesdropper may have access to any one but not more than one subset of the channels but know nothing about the sources, as long as the size of the subset is not above the security level. The question of whether superposition (source separation) coding is optimal for such an AMDCS with threshold perfect secrecy is answered. A class of secure AMDCS (S-AMDCS) with an arbitrary number of encoders is solved, and it is shown that linear codes are optimal for this class of instances. However, in contrast with the secure symmetric MDCS, superposition is shown to be not optimal for S-AMDCS in general. In addition, necessary conditions on the existence of a secrecy key are determined as a design guideline.
标签: Fundamental Limits Secure Class on of
上传时间: 2020-01-04
上传用户:kddlas
In recent years, cellular voice networks have transformed into powerful packet-switched access networks for both voice communication and Internet access. Evolving Universal Mobile Telecommunication System (UMTS) networks and first Long Term Evolution (LTE) installations now deliver bandwidths of several megabits per second to individual users, and mobile access to the Internet from handheld devices and notebooks is no longer perceived as slower than a Digital Subscriber Line (DSL) or cable connection. Bandwidth and capacity demands, however, keep rising because of the increasing number of people using the networks and because of bandwidth-intensive applications such as video streaming. Thus, network manufacturers and network operators need to find ways to continuously increase the capacity and performance of their cellular networks while reducing the cost.
标签: BRINGING NETWORKS Beyond and 3G 4G
上传时间: 2020-05-26
上传用户:shancjb
From the transition of analog to digital communication along with seamless mobility and high computing power of small handheld devices, the wireless communications industry has seen tremendous changes leading to the integration of several telecommunication networks, devices and services over last 30 years. The rate of this progress and growth has increased particularly in the past decade because people no longer use their devices and networks for voice only, but demand bundle contents such as data download/streaming, HDTV, HD video , 3D video conferencing with higher efficiency, seamless connectivity, intelligence, reliability and better user experience. Although the challenges facing service providers and telecommunication companies differ by product, region, market size, and their areas of concentration but time to market, efficient utilization of their assets and revenue expansion, have impacted significantly how to manage and conduct their business while maintaining sufficient margin.
标签: Convergence Networks Beyond 4G of
上传时间: 2020-05-26
上传用户:shancjb
The surge of mobile data traffic forces network operators to cope with capacity shortage. The deployment of small cells in 5G networks is meant to reduce latency, backhaul traffic and increase radio access capacity. In this context, mobile edge computing technology will be used to manage dedicated cache space in the radio access network. Thus, mobile network operators will be able to provision OTT content providers with new caching services to enhance the quality of experience of their customers on the move.
上传时间: 2020-05-26
上传用户:shancjb
At present, there is a strong worldwide push toward bringing fiber closer to indi- vidual homes and businesses. Fiber-to-the-Home/Business (FTTH/B) or close to it networks are poised to become the next major success story for optical fiber com- munications. In fact, FTTH connections are currently experiencing double-digit or even higher growth rates, e.g., in the United States the annual growth rate was 112% between September 2006 and September 2007, and their presence can add value of U.S. $4,000–15,000 to the selling price of a home.
标签: Technologies Broadband Networks Access
上传时间: 2020-05-26
上传用户:shancjb
Employing multiple transmit and receive antennas, namely using multi-input multi-output (MIMO) systems, has proven to be a major breakthrough in providing reliable wireless communication links. Since their invention in the mid-1990s, transmit diversity, achieved through space-time coding, and spatial multiplexing schemes have been the focus of much research in the area of wireless communications.
标签: Communication Systems Coding MIMO for
上传时间: 2020-05-26
上传用户:shancjb
This introduction takes a visionary look at ideal cognitive radios (CRs) that inte- grate advanced software-defined radios (SDR) with CR techniques to arrive at radios that learn to help their user using computer vision, high-performance speech understanding, global positioning system (GPS) navigation, sophisticated adaptive networking, adaptive physical layer radio waveforms, and a wide range of machine learning processes.
标签: Technology Cognitive Radio
上传时间: 2020-05-26
上传用户:shancjb
The term economics is generally understood to mean sound management. This is associated with openness, good faith, accurate figures and integrity in company accounts, with transparency ensured through satisfactory standards of good practice in relation to investors and the clients who have placed their trust in an organization’s managers.
标签: Communication Networks Economy
上传时间: 2020-05-26
上传用户:shancjb