📄 r23.fld
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? "Ideal gas thermodynamic properties of six chlorofluoromethanes,"
? J. Phys. Chem. Ref. Data, 5:571-580, 1976.\
?\
!end of info section
150.0 !lower temperature limit [K]
400.0 !upper temperature limit [K]
0.0 !upper pressure limit [kPa]
0.0 !maximum density [mol/L]
298.97 8.3145 !reducing parameters for T, Cp0
4 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
3.375670 0.00 !c(i), power of T
0.936761 1.00
2.780423 2.00
-0.946568 3.00
@EOS !equation of state specification
FE3 Bender equation of state for R-23 of Platzer et al. (1990).
?LITERATURE REFERENCE \
?Platzer, B., Polt, A., and Maurer, G.,
? "Thermophysical properties of refrigerants,"
? Berlin: Springer-Verlag, 1990.\
?\
!end of info section
190.0 !lower temperature limit [K]
475.0 !upper temperature limit [K]
60000.0 !upper pressure limit [kPa]
16.65 !maximum density [mol/L]
CP3 !pointer to Cp0 model
70.014 !molecular weight [g/mol]
145.0 !triple point temperature [K]
2.5664104 !pressure at triple point [kPa]
22.851535 !density at triple point [mol/L]
191.054 !normal boiling point temperature [K]
0.264 !acentric factor
299.01 4816.2 7.42656 !Tc [K], pc [kPa], rhoc [mol/L]
299.01 7.42656 !reducing parameters [K, mol/L]
8.31451 !gas constant [J/mol-K]
22 5 0 0 0 0 !# terms, # coeff/term for: "normal" terms, critical, spare
-0.133234251368d+1 3.000 0.00 0 0.0 !a(i),t(i),d(i),l(i)
0.210373595421d+1 4.000 0.00 0 0.0
-0.376198728030d+0 5.000 0.00 0 0.0
0.881622087335d+0 0.000 1.00 0 0.0
-0.272053790906d+1 1.000 1.00 0 0.0
0.247468024356d+1 2.000 1.00 0 0.0
-0.234010064393d+1 3.000 1.00 0 0.0
0.303959507238d+0 4.000 1.00 0 0.0
0.317372750273d-1 0.000 2.00 0 0.0
0.329392142221d-1 1.000 2.00 0 0.0
0.205838531860d+0 2.000 2.00 0 0.0
0.133550139894d+0 0.000 3.00 0 0.0
-0.181698216766d+0 1.000 3.00 0 0.0
-0.245123269882d-1 0.000 4.00 0 0.0
0.247477874180d-1 1.000 4.00 0 0.0
0.589916583383d-2 1.000 5.00 0 0.0
0.133234251368d+1 3.000 0.00 2 0.70304082
-0.210373595421d+1 4.000 0.00 2 0.70304082
0.376198728030d+0 5.000 0.00 2 0.70304082
0.574267667948d+0 3.000 2.00 2 0.70304082
-0.762218931280d+0 4.000 2.00 2 0.70304082
0.472710395636d-1 5.000 2.00 2 0.70304082
#AUX !auxiliary model specification
CP3 ideal gas heat capacity function
?LITERATURE REFERENCE \
?Platzer, B., Polt, A., and Maurer, G.,
? "Thermophysical properties of refrigerants,"
? Berlin: Springer-Verlag, 1990.\
?\
!end of info section
190.0 !lower temperature limit [K]
475.0 !upper temperature limit [K]
0.0 !upper pressure limit [kPa]
0.0 !maximum density [mol/L]
1.0 8.31451 !reducing parameters for T, Cp0
5 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
0.40101431d+01 0.0
-0.55274742d-02 1.0
0.74008258d-04 2.0
-0.12590943d-06 3.0
0.69472178d-10 4.0
#TCX !thermal conductivity model specification
TC0 pure fluid thermal conductivity model of Shan et al. (2000).
?LITERATURE REFERENCE \
?Shan, Z., Penoncello, S.G., and Jacobsen, R.T,
? "A Generalized Model for Viscosity and Thermal Conductivity of
? Trifluoromethane (R-23),"
? ASHRAE Transactions, Volume 106:1-11, 2000.
?\
?The uncertainty in thermal conductivity is 2%.
?\
!end of info section
118.02 !lower temperature limit [K]
475.0 !upper temperature limit [K]
120000.0 !upper pressure limit [kPa]
25.0 !maximum density [mol/L]
R23 !pointer to hardcoded thermal conductivity model
7 0 0 0 0 0 0 0 !number of terms for various pieces
299.28 7.5114 1.0 !reducing parameters for T, rho, eta
68.345 0.0 0.00 0.00 0 !rhoL
-2.5370 0.0 0.00 0.00 0 !B1
0.05366 0.0 0.00 0.00 0 !B2
0.94215 0.0 0.00 0.00 0 !C1
0.14914 0.0 0.00 0.00 0 !C2
2508.58 0.0 0.00 0.00 0 !delta G
25. 0.0 0.00 0.00 0 !etaMax
NUL !pointer to critical enhancement auxiliary function (none used)
#ETA !viscosity model specification
VS0 pure fluid viscosity model of Shan et al. (2000).
?LITERATURE REFERENCE \
?Shan, Z., Penoncello, S.G., and Jacobsen, R.T,
? "A Generalized Model for Viscosity and Thermal Conductivity of
? Trifluoromethane (R-23),"
? ASHRAE Transactions, Volume 106:1-11, 2000.
?\
?The uncertainty in viscosity is 1%.
?\
!end of info section
118.02 !lower temperature limit [K]
475.0 !upper temperature limit [K]
120000.0 !upper pressure limit [kPa]
25.0 !maximum density [mol/L]
R23 !pointer to hardcoded thermal conductivity model
1 0 0 5 0 0 0 0 !number of terms for various pieces
CI1 !pointer to reduced effective collision cross-section model
0.4278 !Lennard-Jones coefficient sigma [nm]
243.91 !Lennard-Jones coefficient epsilon/kappa [K]
1.0 1.0 !reducing parameters for T, eta
0.2233755 0.50d0 !Chapman-Enskog term
299.28 7.5114 1.0 !reducing parameters for T, rho, eta
32.174 0.0 0.00 0.00 0 !rhoL
1.3163 0.0 0.00 0.00 0 !C1
0.1832 0.0 0.00 0.00 0 !C2
771.23 0.0 0.00 0.00 0 !delta G
3.967 0.0 0.00 0.00 0 !etaMax
NUL !pointer to critical enhancement auxiliary function (none used)
#AUX !collision integral specification
CI1 collision integral model of Shan et al. (2000).
?LITERATURE REFERENCE \
?Shan, Z., Penoncello, S.G., and Jacobsen, R.T,
? "A Generalized Model for Viscosity and Thermal Conductivity of
? Trifluoromethane (R-23),"
? ASHRAE Transactions, Volume 106:1-11, 2000.
?\
!end of info section
118.02 !lower temperature limit [K]
475.0 !upper temperature limit [K]
0.0 !(dummy) upper pressure limit
0.0 !(dummy) maximum density
5 !number of terms
0.4425728 0 !coeff, power of Tstar
-0.5138403 1
0.1547566 2
-0.02821844 3
0.001578286 4
@TRN !transport model specification
ECS Extended Corresponding States model (R134a reference); fitted to data.
?LITERATURE REFERENCES \
?Klein, S.A., McLinden, M.O., and Laesecke, A.,
? "An improved extended corresponding states method for estimation of
? viscosity of pure refrigerants and mixtures,"
? Int. J. Refrigeration, 20:208-217, 1997.
?\
?McLinden, M.O., Klein, S.A., and Perkins, R.A.,
? "An extended corresponding states model for the thermal conductivity
? of refrigerants and refrigerant mixtures,"
? Int. J. Refrigeration, 23:43-63, 2000.
?\
?DATA SOURCES FOR THERMAL CONDUCTIVITY\
?The ECS parameters for thermal conductivity were based on the data of:\
?\
?Geller, V. and Peredrii, V.G. (1975).
? Thermal conductivity of Freon 13 and Freon 23 (in Russian).
? Izv. Vyssh. Uchebn Zaved Energetika, 18:113-116.\
?\
?Makita, T., Tanaka, Y., Morimoto, Y., Noguchi, M., and Kubota, H. (1981).
? Thermal conductivity of gaseous fluorocarbon refrigerants R12, R13, R22,
? and R23 under pressure. Int. J. Thermophysics, 2:249-268.\
?\
?Average absolute deviations of the fit from the experimental data were:\
? Geller: 3.84%; Makita: 1.45%; Overall: 2.50%\
?\
?Lennard-Jones parameters are from Shan, et al. ASHAE Trans. 106:1 (2000)\
?\
!end of info section
136.0 !lower temperature limit [K] (based on Ttp/Tc of ref fluid)
400.0 !upper temperature limit [K]
60000.0 !upper pressure limit [kPa]
20.0 !maximum density [mol/L] (limit of ECS-thermo fit)
FEQ R134a.fld
VS1 !model for reference fluid viscosity
TC1 !model for reference fluid thermal conductivity
1 !Lennard-Jones flag (0 or 1) (0 => use estimates)
0.4278 !Lennard-Jones coefficient sigma [nm] for ECS method
243.91 !Lennard-Jones coefficient epsilon/kappa [K] for ECS method
2 0 0 !number of terms in f_int term in Eucken correlation, spare1, spare2
6.0570d-4 0.0 0.0 0.0 !coeff, power of T, spare 1, spare 2
1.8604d-6 1.0 0.0 0.0
1 0 0 !number of terms in psi (visc shape factor): poly,spare1,spare2
1.0000d+0 0.0 0.0 0.0 !coeff, power of Tr, power of Dr, spare
3 0 0 !number of terms in chi (t.c. shape factor): poly,spare1,spare2
1.3801d+0 0.0 0.0 0.0 !coeff, power of Tr, power of Dr, spare
-2.7975d-1 0.0 1.0 0.0
4.8798d-2 0.0 2.0 0.0
#STN !surface tension specification
ST1 surface tension model of Okada and Watanabe (1988).
?LITERATURE REFERENCE \
?Okada, M. and Watanabe, K.,
? "Surface tension correlations for several fluorocarbon refrigerants,"
? Heat Transfer-Japanese Research, 17:35-52, 1988.\
?
!end of info section
118.02 !lower temperature limit [K]
299.0 !upper temperature limit [K]
0.0 !(dummy) upper pressure limit
0.0 !(dummy) maximum density
1 !number of terms in surface tension model
299.01 !critical temperature used by Okada & Watanabe (dummy)
0.06562 1.29 !sigma0 and n
#PS !vapor pressure equation
PS5 vapor pressure equation of Penoncello et al. (2002).
?LITERATURE REFERENCE \
?See EOS
?\
!end of info section
118.02 !lower temperature limit [K]
299.0 !upper temperature limit [K]
0.0 !(dummy) upper pressure limit
0.0 !(dummy) maximum density
299.293 4832.0 !reducing parameters
4 0 0 0 0 0 !number of terms in equation
-7.2631 1.0 !coefficients and exponents
1.3140 1.5
-0.78507 2.4
-3.1991 3.9
#DL !saturated liquid density equation
DL1 saturated liquid density equation of Penoncello et al. (2002).
?LITERATURE REFERENCE \
?See EOS
?\
!end of info section
118.02 !lower temperature limit [K]
299.0 !upper temperature limit [K]
0.0 !(dummy) upper pressure limit
0.0 !(dummy) maximum density
299.293 7.52 !reducing parameters
3 0 0 0 0 0 !number of terms in equation
2.2636 0.37 !coefficients and exponents
0.47007 0.94
0.28660 3.1
#DV !saturated vapor density equation
DV3 saturated vapor density equation of Penoncello et al. (2002).
?LITERATURE REFERENCE \
?See EOS
?\
!end of info section
118.02 !lower temperature limit [K]
299.0 !upper temperature limit [K]
0.0 !(dummy) upper pressure limit
0.0 !(dummy) maximum density
299.293 7.52 !reducing parameters
4 0 0 0 0 0 !number of terms in equation
-3.5136 0.43 !coefficients and exponents
-7.7491 1.4
-24.871 3.7
-65.637 8.0
@END
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